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Now That's What I Call Music! 66 or Now 66 was released on 2 April 2007 on Compact Disc and in digital download format. The album is the 66th edition of the original (UK) Now! series.
Now 66 features seven songs which reached number one on the UK Singles Chart: "Grace Kelly", "Ruby", "Walk This Way", "Patience", "Smack That", "A Moment Like This" and "I'm Gonna Be (500 Miles)".
The Proclaimers song "I'm Gonna Be (500 Miles)" previously appeared on Now 13 in its original form.
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